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Casino Royale introduces James Bond before he holds his license to kill. But Bond is no less dangerous, and with two professional assassinations in quick succession, he is elevated to '00' status. Bond's first 007 mission takes him to Uganda where he is to spy on a terrorist, Mollaka. Not everything goes to plan and Bond decides to investigate, independently of MI6, in order to track down the rest of the terrorist cell. Following a lead to the Bahamas, he encounters Dimitrios and his girlfriend, Solange. He learns that Dimitrios is involved with Le Chiffre, banker to the world's terrorist organizations. Secret Service intelligence reveals that Le Chiffre is planning to raise money in a high-stakes poker game in Montenegro at Le Casino Royale. MI6 assigns 007 to play against him, knowing that if Le Chiffre loses, it will destroy his organization. 'M' places Bond under the watchful eye of the beguiling Vesper Lynd. At first skeptical of what value Vesper can provide, Bond's interest in her deepens as they brave danger together and even torture at the hands of Le Chiffre. In Montenegro, Bond allies himself with Mathis MI6's local field agent, and Felix Leiter who is representing the interests of the CIA. The marathon game proceeds with dirty tricks and violence, raising the stakes beyond blood money and reaching a terrifying climax

Casino Royale at IMDb Wikipedia

• Daniel Craig as James Bond: A British agent who, after being assigned 00-status, is sent on a mission to arrest a bomb maker in Madagascar, where he stumbles upon Le Chiffre's terrorist cell and is then sent to defeat him in a high-stakes poker game at Casino Royale.
• Eva Green as Vesper Lynd: An agent for HM Treasury assigned to supervise Bond and finance his poker table exploits. She is actually affiliated to global terrorists and thought to be based on SOE agent Krystyna Skarbek.
• Mads Mikkelsen as Le Chiffre: A banker who services many of the world's terrorists. He is a mathematical genius and chess expert, and uses these skills when playing poker.
• Judi Dench as M: The strict head of MI6. Though she feels she has promoted Bond too soon and expresses abhorrence of his rash actions, she acts as an important maternal figure in his life.
• Ivana Miličević as Valenka: Le Chiffre's girlfriend and henchwoman.
• Jeffrey Wright as Felix Leiter: A quiet CIA operative participating in the poker tournament while assisting Bond. This is the first official Bond film in which Leiter is played by a black actor.
• Giancarlo Giannini as René Mathis: Bond's ally in Montenegro.
• Simon Abkarian as Alex Dimitrios: Another contractor in the international terrorist underworld and associate of Le Chiffre, based in the Bahamas.
• Caterina Murino as Solange Dimitrios: Dimitrios's wife, whom Bond seduces. She is killed by Le Chiffre for unintentionally revealing one of his plans to Bond.
• Isaach De Bankolé as Steven Obanno: A feared leader of the Lord's Resistance Army, introduced to Le Chiffre by Mr. White to account his finances.
• Jesper Christensen as Mr. White: A mysterious liaison for an unnamed terrorist organization.
• Sébastien Foucan as Mollaka: A bombmaker pursued by Bond through a construction site in Madagascar.
• Ludger Pistor as Mendel: A Swiss banker responsible for all monetary transactions during and after the poker tournament.
• Claudio Santamaria as Carlos: A terrorist employed by Le Chiffre to blow up an aircraft.

Two major exclusions from the film are the characters of Q and Miss Moneypenny. Their exclusion makes Casino Royale the second film in the series without Q (Live and Let Die being the first), and the first without Moneypenny. In October 2005, producer Michael G. Wilson stated that the characters were not in the movie because they were not in the book, though Moneypenny was mentioned by Bond in the novel. The decision to leave Moneypenny's character out from the film coincided with the announcement by actress Samantha Bond, who had portrayed the character in the previous four films, that she would not reprise the role.Casino Royale includes a cameo by British entrepreneur Richard Branson (seen being frisked at Miami airport) The cameo was cut out of the in-flight version shown on British Airways aircraft, as was a shot of the Virgin Atlantic aircraft Branson supplied.