The second episode of the season, "Need to Know." That episode is exponentially better than "Withdrawal," and features a more engrossing storyline: politics. Neal goes undercover to take down a corrupt politician, with some help from Agent Diana Lansing (Marsha Thomason, LOST) who I'm happy to see on the show as a regular. Despite the fact that the character Lansing is a lesbian, she shares real chemistry with Bomer's Neal. Not necessarily sexual chemistry, but the two play off each other incredibly well. The episode is a lot more fun, and it might teach you a little bit about hotel rooms. You'll also get to see Neal do an impression of Mario (the video game plumber) toward the end of this episode, and it's totally hilarious.
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