How is PEOPLE Magazine's "Sexiest Man Alive" chosen? 25 Years of Sexy: PEOPLE Magazine's Sexiest Man Alive!, a one-hour special hosted by Kim Kardashian, airs WEDNESDAY, NOVEMBER 17 (10:00-11:00 p.m., ET) on the ABC Television Network and celebrates the 25th anniversary of this successful franchise. The special goes behind the scenes of the "2010 Sexiest Man Alive" edition to reveal for the first time ever PEOPLE magazine's selection process, and features highlights from the iconic issue since its debut in1985.