Gotham revolves around the Gotham’s future commissioner, Jim Gordon and takes place within the Batman universe. Fox hopes to use Gotham as a vehicle for exploring famous Batman villains like the Riddler, Catwoman, and the Penguin.
I'm going to stick to must watch shows only rather than list my entire Sci-fi library. If there is something not on this list it may be because I haven't seen it either, like any of the Star Trek series. I've seen bits but not enough to give my vote against or for it.
Also I have a few shows multiple times to show webisodes and things that run concurrently with the show